Triphenylbismuthine: Difference between revisions

Triphenylbismuthine
Names
	Other names Triphenylbismuthine
Identifiers
CAS Number	603-33-8;
ECHA InfoCard	100.009.122
CompTox Dashboard (EPA)	DTXSID6042498 ;
Properties
Chemical formula	C18H15Bi
Molar mass	440.298 g·mol−1
Appearance	white solid
Density	1.585 g/cm³
Melting point	77.6 °C (171.7 °F; 350.8 K)
	Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). Infobox references

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Revision as of 23:41, 7 February 2024

Triphenylbismuth, an example of an organometallic bismuth(III) compound

Triphenylbismuthine is an organobismuth compound with the formula Bi(C₆H₅)₃. It is a white, air-stable solid that is soluble in organic solvents. It is prepared by treatment of bismuth trichloride with phenylmagnesium bromide.^[1]

It serves as a phenyl donor in cross coupling reaction]]s catalyzed by Pd(0).^[2] It reacts with trifluoromethanesulfonic acid to give bismuth triflate:^[3]

Bi(C₆H₅)+3 3 HO₃SCF₃ → Bi(O₃SCF₃)₃ + 3 C₆H₆

References

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^ . doi:10.1016/s0040-4039(98)02397-1. {{cite journal}}: Cite journal requires |journal= (help); Missing or empty |title= (help)

[1] . doi:10.1002/047084289X.rt358.pub2. {{cite journal}}: Cite journal requires |journal= (help); Missing or empty |title= (help)

[2] . doi:10.1021/ol1004164. {{cite journal}}: Cite journal requires |journal= (help); Missing or empty |title= (help)

[3] . doi:10.1016/s0040-4039(98)02397-1. {{cite journal}}: Cite journal requires |journal= (help); Missing or empty |title= (help)

[1]